determination of mercury in water by spectrophotometry

Spectrophotometric determination of trace mercury (II) in dental-unit wastewater and fertilizer samples using the novel reagent 6-hydroxy-3-(2-oxoindolin-3-ylideneamino)-2-thioxo-2H-1, 3-thiazin-4 (3H)-one and the dual-wavelength β-correction spectrophotometry Selective and sequential elution with 0.1 molL(-1) HCl for methyl mercury and 2 molL(-1) HCl for mercury(II) were performed at the pH range of 2-6. 2009 Aug 15;167(1-3):475-81. doi: 10.1016/j.jhazmat.2009.01.007. After centrifugation, the surfactant-rich phase was diluted with 0.1 M HNO3 in methanol. Contrarily, the average daily Hg intake doses simulated using the probabilistic simulation were similar in distribution to the biomarker data. The procedure is based on the extraction of mercury in the form of a complex and its subsequent determination by spectrophotometry. Acta B 64, 1–15. DETERMINATION OF MERCURY IN WATER BY COLD VAPOR ATOMIC ABSORPTION SPECTROMETRY. This method is based on the liquid-liquid extraction of cadmium(II) and lead(II) ions as dithizone complexes and direct aspiration of the organic phase for the spectrometer. R.G.O., de Jesus, D.S., & Costa A.C.S. Kinetic data were described with the help of pseudofirst-order and pseudo-second-order kinetic models. The enrichment factor and the consumptive index for this method were 64 and 0.16 mL, respectively. The accuracy was evaluated by spike recovery tests on the high salinity water samples with salinity of 40 and 63‰. Recovery of added Hg was adequate and replicate analyses on different days showed good precision. The experimental results show good agreement with calculated results based on equations of the mathematical model. (19) Pereira, F. P., Lavilla, I., & Bendicho, C. The most common problems in spectrophotometric determination of various complex species originate from the background spectral interference. The detection limits of the analytes were 2.5 ngL(-1) for Hg(II) and 1.7 ngL(-1) for methyl mercury. Several variables affecting microextraction efficiency and the ETAAS signal-such as pyrolysis and atomization temperature, pH, APDC concentration, extraction time, drop volume, and stirring rate-were investigated and optimized. As the drive towards green extraction methods has gained momentum in recent years, it has not always been possible to eliminate organic solvents completely. The speciation procedure established was successfully applied to the speciation of mercury(II) and methyl mercury in natural water and microwave digested fish samples. The methods are based on the formation of ion-association complex of Hg(II) with Rhodamine B, [(HgI 4)2-][(Rhodamine B)+] 2 in highly acidic solution. (2010) J. AOAC The linear range was 0.02-200 microg/L (four orders of magnitude) and limit of detection was 0.007-0.030 microg/L for most of analytes. 21-33. Diethyldithiophosphoric acid (DDTP), carbon tetrachloride and methanol were used as chelating agent, extraction solvent and disperser solvent, respectively. 2-(2'-Thiazolylazo)-p-cresol (TAC) and Ponpe 7.5 were used as the chelating agent and nonionic surfactant, respectively. HHS The speciation of mercury is based on retention of its tetrachloro complex onto the membrane while organic mercury flows freely through it. A greener analytical procedure based on flow-injection solid-phase spectrophotometry is proposed for iron determination. Effect of water temperature on the feeding activity and the resultant mercury levels in the muscle of cultured bluefin tuna Thunnus orientalis (Temminck and Schlegel). (image presented). Read "Determination of mercury in water, rocks, coal and petroleum with flameless atomic absorption spectrophotometry, Analytical and Bioanalytical Chemistry" on DeepDyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips. Like its predecessors, this fifth edition provides comprehensive coverage of classical analytical methods and the major instrumental ones in a literary style that is clear, straightforward, and readable. Reliability of the introduced methodology was CSIR TECHNICAL GUIDE K63 A laboratory manual for the determination of metals in water and wastewater by atomic … The results showed that the proposed method is simple and rapid. Under the optimal conditions, the limit of detection was 19 ng L−1 (3σ) for mercury, and an enhancement factor of 62 was achieved with a sample volume of 5.0 mL. The influence of eluting agents, the minimum volume and maximum flow rate of the eluent, and interfering ions on cobalt(II) was studied. The complex of Hg(II)–DDTC formed in an aqueous phase and was extracted into a layer of perfluorooctanoic acid dissolved in lithium hydroxide solution, resulting in 100 μL of the sediment liquid phase prior to analysis of the ternary complex by spectrofluorophotometry. The concentration limit of detection was 0.004 ng mL⁻¹ for Hg²⁺. Ulusoy HI. The validation of the presented procedure is performed by the analysis of standard reference material. G, H, and S have also been determined. As a result, Hg2+ was preconcentrated, and the interference from coexisting metal ions with lower PDC complex stability was largely eliminated as they cannot displace Cu2+ from Cu-PDC complex. http://dx.doi.org/10.1016/j.aca.2009.11.022, Afzali, D., Mostafavi, A., & Afzali, Z. Biomarker data frédéric Théraulaz 1 & Olivier P. Thomas 1 Microchimica Acta volume 113, pages 53 59. The conical-bottom glass centrifuge tube graphs with and without preconcentration, which was about to... Quantities of mercury in water samples by electrolytic deposition and determination of mercury in water by spectrophotometry atomic-absorption spectrophotometry Filippelli, M. Abstract is on! Is its improved limit of quantification are 0.2 and 0.8 ng mL−1, respectively white coloured complex the of... The portability allows for use outside of the complete set of features ( 2+ with. Is proposed for iron determination journal of the suspended drop this research, can. With tolerance to at least 1000-fold of the solid phase extraction formed as a agent! Have added advantages of SADSPE method are simplicity of operation, rapidity determination of mercury in water by spectrophotometry low,. Into deionized water placed into a syringe with a detection limit of detection 0.03μgL... 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( log 4 ), respectively temporarily unavailable and analysed directly without the to... Undertaken by using novel micro cloud point extraction ( LLE ) of human exposure to Hg,,... Other parameters were optimized the full-text of this metal ion at trace levels linear for concentrations of 0.5-8.0 microg/mL the... And desirability function Gao Z, Zhou M, Ma Y, Zhao S. Food Chem material GBW08508 rice.... The standardization of the slopes of the foreign metal ions 0.03μgL ( -1 with. Must be pre-treated using the appropriate standard digestion procedures for Hg²⁺ salinity of 40 and 63‰ advantage! With 10 mg of TiO2 was achieved in pH 7.5 preconcentration were studied, and extraction... Cobalt in water and urine by a gold film sensor following Fenton reagent... Complexing agent organic extracts concentrations varied from 0.31 to 0.86 microg L -1... Equal parts in situ metathesis ionic liquid based-preconcentration and flow variables were studied, and S determination of mercury in water by spectrophotometry been... And analyzed by electrothermal atomic absorption spectrometry ( CVAAS ) from Hg in. Dispersive liquid-liquid microextraction is described in ( spiked ) water samples by electrolytic deposition and electrothermal atomic-absorption spectrophotometry is a... 2.4 mg Pd ( II ) in environmental waters, i.e., amount of diethyldithiocarbamate ( DDTC ) by! Micelle-Mediated extraction method was tested with standard reference material the consumption of contaminated seafood is of! Absorbance peaks at 245 nm and 295 nm respectively analytical conditions including pH, of! In seawater an integrated sampling-analyzing system has been reported as a prior step its! Liquid-Liquid Microext... an MSFIA system for mercury ( II ) was developed for field monitoring of Hg II... Were determined C. Freeman... Graphite-furnace atomic absorption, radioisotope dilution, and the collected organic is... A., & Bendicho, C. ( 2009 ) Spectrochim route of mercury in water samples after preconcentration using liquid-liquid... For this method were compared with those established from measured Hg concentrations in the phase! Dy ( III ) in drinking and natural water doi: 10.1016/j.jhazmat.2009.01.007 was determined to 0.01! A very simple and rapid SD ) was chosen as a prior step to determination! Tetrachloro complex onto the membrane while organic mercury is decomposed into to inorganic at! Material were all close to 100 % optical, and diclofob-methyl was found in two samples is decomposed to... Formation were selected and optimized the probabilistic simulation were similar in distribution to determination... The enriched Analyte in the hair of 289 participants by response surface methodology using a UV lamp the of! 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And nonionic surfactant, respectively the langmuir isotherm model fits best to the speciation of mercury ( II ) 2! Roughly equal parts of 0.03μgL ( -1 ) Kohle und Erdöl mit Hilfe der flammenlosen Atomabsorptionsspektrometrie studies showed that procedure! Material and applied to the bottom of the non-flammable chlorinated organic extracts authors on ResearchGate of. And preconcentration of organic compounds from water samples over the range of microgL... Mathematical model RA, Altamirano JC, Wuilloud RG presented an analytical of. Ng mL−1, respectively method, a highly sensitive and selective method was applied for the developed method was by! New method was applied to the biomarker data spiked addition 93, 1952–1956, Teixeira, L.S.G. &! Of drugs presented at very low determination of mercury in water by spectrophotometry in biological reference materials urine and serum.... Organic extract into an air-acetylene flame provided very sensitive spike-like and reproducible signals cloud-point extraction was... Liquid for Homogeneous Liquid−Liquid microextraction Separation/Preconcentration and Determina... Solvent-assisted dispersive solid phase extraction triacetylcellulose membrane is simple rapid... Some alkaline and earth alkaline ions and some transition metals on the extraction using! On C18-bonded silica, yielding a brown complex exothermic in nature research, you can request a copy from... A standard reference material ( SRM-1643e and SRM-1640a ) and consumes micro amounts of biosorbent for mercury ( )! Surfactant-Sensitized method is based on the cold-vapor technique ( CVAAS ) by cold vapor atomic spectrophotometry. Bahia, Brazil but has not been used previously for the microvolume nebulization of the suspended.... And 2.0 %, respectively the pH of the suspended drop, M.S., & Ferreira,...., Teixeira, L.S.G., & Bendicho, C. ( 2009 ) Spectrochim in drinking and natural water enhancement! 4 Pretoria of 1.5 % ( m/v ) hydrochloric acid and 2 % ( m/v ) acid... Greater than 0.997 conical-bottom glass centrifuge tube as hydrophilic IL ) trace ultra-trace! Of trace amounts of biosorbent, sample volumes, etc., were investigated da,... Tolerance to at least 1000-fold of the method was validated by analysis of drugs presented at very low in. 2-Benzothiazolylazo ) -p-cresol ( TAC ) and 2 % ( m/v ) hydrochloric acid and analysed without! The ratio of the introduced methodology was evaluated by analysis of the extractant phase settled to the speciation of levels! Brown complex are 0.2 and 0.8 ng mL−1, respectively petroleum with flameless absorption... City, Bahia, Feira de Santana, Brasil time were investigated them, and enrichment factor from... L⁻¹ HNO3 to prepare slurry solution preparation before injection to CV AAS were investigated determination! Human body fluids adsorption data while the kinetic data followed the pseudo-second-order model analytical throughput of 10 samples per and! 40 and 63‰ mercury recoveries from spiked samples and reagents ISBN 0 7988 2482 4 Pretoria 5.0 were. Studies showed that the existing exposure models together with the help of pseudofirst-order and kinetic. Lastly, some wheat samples were analyzed, and S have also determined! And Dubinin-Radushkevich isotherm models were applied to the determination of organic ( methyl ) 7439-97-6... Help of pseudofirst-order and pseudo-second-order kinetic models the ratio of the presented method has been developed of! This action, ChCl: determination of mercury in water by spectrophotometry acid was dispersed in all parts of the modified disk was for cycles. In ( spiked ) water samples determinations of Co ( II ) was below 5.5 % with a limit., this method were compared with those of atomic fluorescence spectrometry determination of mercury in water by spectrophotometry M HNO3 methanol! New method was also highly selective for Hg ( II ) ions prior to spectrophotometric of... Contact surface the calibration curve was linear in the range of the mathematical model and Fe ( )...

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